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The purpose of this paper is to calculate the Hugoniot relations of polyurea; also to investigate the atomic-scale energy change, the related chain conformation evolution and the hydrogen bond dissociation of polyurea under high-speed shock.

The atomic-scale simulations are achieved by molecular dynamics (MD). Both non-equilibrium MD and multi-scale shock technique are used to simulate the high-speed shock. The energy dissipation is theoretically derived by the thermodynamic and the Hugoniot relations. The distributions of bond length, angle and dihedral angle are used to characterize the chain conformation evolution. The hydrogen bonds are determined by a geometrical criterion.

The Hugoniot relations calculated are in good agreement with the experimental data. It is found that under the same impact pressure, polyurea with lower hard segment content has higher energy dissipation during the shock-release process. The primary energy dissipation way is the heat dissipation caused by the increase of kinetic energy. Unlike tensile simulation, the molecular potential increment is mainly divided into the increments of the bond energy, angle energy and dihedral angle energy under shock loading and is mostly stored in the soft segments. The hydrogen bond potential increment only accounts for about 1% of the internal energy increment under high-speed shock.

The simulation results are meaningful for understanding and evaluating the energy dissipation mechanism of polyurea under shock loading, and could provide a reference for material design.

The purpose of this paper is to synthesise a disperse dye based on benzisothiazole and to characterise its crystal morphology, dispersing stability, to study the relationship between the chemical structure and the dyeing property of the dye.

The disperse dye based on benzisothiazole, 3-(3-methyl-4-N-ethyl-N-benzyl-phenyldiazenyl)-5-nitro-2,1-benzisothiazoles, was synthesized. The disperse dye based on benzisothiazole, 3-(3-methyl-4-N-ethyl-N-benzyl-phenyldiazenyl)-5-nitro-2,1-benzisothiazoles, was synthesised. The chemical structure of the dye obtained was characterised by infrared spectrum Fourier transform infrared spectroscopy and nuclear magnetic resonance (1HNMR), and the crystal morphology was observed by Field Emission Scanning Electron Microscopy. Sodium salt of polycondensated naphthalenesulphonic acid (dispersing agent sodium salt of polycondensated naphthalenesulphonic acid [MF]) and a sulphonated amino polyether (anionic surfactant B600) were employed to grind and disperse the dye crystals. The dispersion property of the dye particles was characterised. Dyeing property of the dispersion system was also studied.

The dye formed spherical crystals that were made up of a large number of acicular crystals similar to spherical chrysanthemum. The crystals had warping crystal centres inside the spheres. The particle sizes of the dispersion with the mixture of B600 and MF had an uniform distribution and were smaller than that of the dispersion with only single dispersing agent MF. Dyeing with the dispersion system had an excellent reproducibility under alkalinic condition.

An alkalinic dyeing method for poly(ethylene terephthalate) (PET) with disperse dyes as a cleaner wet process had been developed. Such a process combined pretreatment and dyeing process using the alkali-stable disperse dyes and reduced the consumption of water and energy and improved production efficiency.

The crystal morphology, dispersion and dyeing properties of the synthesised disperse dye for dyeing PET fabric under alkalinic condition were discussed. This disperse dye has an important potential application in alkalinic dyeing method.

In order to make grey relational analysis applicable to the interval grey number, this paper discusses the model of grey relational degree of the interval grey number and uses it to analyze the related factors of China's technological innovation ability.

First, this paper gives the definitions of the lower bound domain, the value domain, the upper bound domain of interval grey number and the generalized measure and the generalized greyness of interval grey number. Then, based on the grey relational theory, this paper proposes the model of greyness relational degree of the interval grey number and analyzes its relationship with the classical grey relational degree. Finally, the model of greyness relational degree is applied to analyze the related factors of China's technological innovation ability.

The results show that the model of greyness relational degree has strict theoretical basis, convenient calculation and easy programming and can be applied to the grey number sequence, real number sequence and grey number and real number coexisting sequence. The relational order of the four related factors of China's technological innovation ability is research and development (R&D) expenditure, R&D personnel, university student number and public library number, and it is in line with the reality.

The results show that the sequence values of greyness relational degree have large discreteness, and it is feasible and effective to analyze the related factors of China's technological innovation ability.

The paper succeeds in realizing both the model of greyness relational degree of interval grey number with unvalued information distribution and the order of related factors of China's technological innovation ability.

With the advent of AI-federated technologies, it is feasible to perform complex tasks in industrial Internet of Things (IIoT) environment by enhancing throughput of the network and by reducing the latency of transmitted data. The communications in IIoT and Industry 4.0 requires handshaking of multiple technologies for supporting heterogeneous networks and diverse protocols. IIoT applications may gather and analyse sensor data, allowing operators to monitor and manage production systems, resulting in considerable performance gains in automated processes. All IIoT applications are responsible for generating a vast set of data based on diverse characteristics. To obtain an optimum throughput in an IIoT environment requires efficiently processing of IIoT applications over communication channels. Because computing resources in the IIoT are limited, equitable resource allocation with the least amount of delay is the need of the IIoT applications. Although some existing scheduling strategies address delay concerns, faster transmission of data and optimal throughput should also be addressed along with the handling of transmission delay. Hence, this study aims to focus on a fair mechanism to handle throughput, transmission delay and faster transmission of data. The proposed work provides a link-scheduling algorithm termed as delay-aware resource allocation that allocates computing resources to computational-sensitive tasks by reducing overall latency and by increasing the overall throughput of the network. First of all, a multi-hop delay model is developed with multistep delay prediction using AI-federated neural network long–short-term memory (LSTM), which serves as a foundation for future design. Then, link-scheduling algorithm is designed for data routing in an efficient manner. The extensive experimental results reveal that the average end-to-end delay by considering processing, propagation, queueing and transmission delays is minimized with the proposed strategy. Experiments show that advances in machine learning have led to developing a smart, collaborative link scheduling algorithm for fairness-driven resource allocation with minimal delay and optimal throughput. The prediction performance of AI-federated LSTM is compared with the existing approaches and it outperforms over other techniques by achieving 98.2% accuracy.

With an increase of IoT devices, the demand for more IoT gateways has increased, which increases the cost of network infrastructure. As a result, the proposed system uses low-cost intermediate gateways in this study. Each gateway may use a different communication technology for data transmission within an IoT network. As a result, gateways are heterogeneous, with hardware support limited to the technologies associated with the wireless sensor networks. Data communication fairness at each gateway is achieved in an IoT network by considering dynamic IoT traffic and link-scheduling problems to achieve effective resource allocation in an IoT network. The two-phased solution is provided to solve these problems for improved data communication in heterogeneous networks achieving fairness. In the first phase, traffic is predicted using the LSTM network model to predict the dynamic traffic. In the second phase, efficient link selection per technology and link scheduling are achieved based on predicted load, the distance between gateways, link capacity and time required as per different technologies supported such as Bluetooth, Wi-Fi and Zigbee. It enhances data transmission fairness for all gateways, resulting in more data transmission achieving maximum throughput. Our proposed approach outperforms by achieving maximum network throughput, and less packet delay is demonstrated using simulation.

Our proposed approach outperforms by achieving maximum network throughput, and less packet delay is demonstrated using simulation. It also shows that AI- and IoT-federated devices can communicate seamlessly over IoT networks in Industry 4.0.

The concept is a part of the original research work and can be adopted by Industry 4.0 for easy and seamless connectivity of AI and IoT-federated devices.